Kagan ML? Model
Model rationalizing nonlinear ee effects via homochiral/heterochiral catalyst aggregates.
Context: Guides interpretation of catalyst behavior in development.
Example: Dimeric catalyst equilibria giving nonlinear plots.
Related Terms: Nonlinear Effects, Enantioselectivity.
Reference: Kagan, Acc. Chem. Res. (1997).
Karplus Relationship
Empirical relationship between vicinal ³J coupling and dihedral angle.
Context: Supports stereochemical assignment from NMR coupling constants.
Example: ³JHH ~ 10 Hz for anti arrangement.
Related Terms: J-Coupling, Conformation.
Reference: Karplus, J. Chem. Phys. (1959).